|
|
behenoyl-CoA + NADP+ <=> trans-docos-2-enoyl-CoA + NADPH + H+
|
1.3.1.93
very-long-chain enoyl-CoA reductase
|
–
|
MK
|
|
BRENDA:
BR50149
KEGG:
R10828
MetaCyc:
RXN-13307
|
|
|
|
behenoyl-CoA + sphingosine <=> a_very-long-chain_ceramide + CoA + H+
|
2.3.1.297
very-long-chain ceramide synthase
|
–
|
|
|
BRENDA:
BR52919
MetaCyc:
RXN-20364
|
|
|
|
behenoyl-CoA + malonyl-CoA <=> a_very-long-chain_3-oxoacyl-CoA + CO2 + CoA
|
2.3.1.199
very-long-chain 3-oxoacyl-CoA synthase
|
–
|
K
|
|
BRENDA:
BR50172
KEGG:
R10825
|
|
|
|
behenoyl-CoA + H2O <=> CoA + behenic_acid
|
3.1.2
3.1.2.2
palmitoyl-CoA hydrolase
|
–
–
|
K
|
|
KEGG:
R08184
SABIO-RK:
6600
|
|
|
|
very-long-chain_fatty_aldehyde + CoA + NADP+ <=> behenoyl-CoA + NADPH + H+
|
1.2.1
|
–
|
M
|
|
MetaCyc:
RXN-1021
|
|
|
|
stearoyl-CoA + malonyl-CoA <=> behenoyl-CoA + CO2 + CoA
|
not assigned
|
–
|
|
|
MetaCyc:
RXN-1026
|
|
|
|
behenoyl-CoA + reduced_[NADPH-hemoprotein_reductase] + O2 <=> 22-hydroxy-docosanoyl-CoA + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14
|
–
|
M
|
|
MetaCyc:
RXN-12155
|
|
|
|
malonyl-CoA + behenoyl-CoA + H+ <=> 3-oxo-lignoceroyl-CoA + CO2 + CoA
|
2.3.1.199
very-long-chain 3-oxoacyl-CoA synthase
|
–
|
M
|
|
MetaCyc:
RXN-13297
|
|
|
|
behenoyl-CoA + sn-glycerol_3-phosphate <=> CoA + 2-docosanoyl-glycerol_3-phosphate
|
2.3.1.198
glycerol-3-phosphate 2-O-acyltransferase
|
–
|
|
|
MetaCyc:
RXN-13736
|
|
|
|
very-long-chain_fatty_acid + CoA + ATP <=> behenoyl-CoA + diphosphate + AMP
|
6.2.1.M30
|
–
|
|
|
MetaCyc:
RXN-16415
|
|
|
|
behenoyl-CoA + sphinganine <=> N-behenoyl-D-erythro-sphingosine + CoA + H+
|
2.3.1.297
very-long-chain ceramide synthase
|
–
|
|
|
MetaCyc:
RXN-20369
|
|
|
|
behenoyl-CoA + phytosphingosine <=> very-long-chain_phytoceramide + CoA + H+
|
2.3.1.297
very-long-chain ceramide synthase
|
–
|
M
|
|
MetaCyc:
RXN3O-328
|
|
|
|
very-long-chain_fatty_alcohol + NADP+ + CoA <=> behenoyl-CoA + NADPH + H+
|
1.2.1
|
–
|
M
|
|
MetaCyc:
RXNQT-4192
|
|
|
|
behenoyl-CoA + sphinganine <=> a_very-long-chain_sphinganine + CoA
|
2.3.1.297
very-long-chain ceramide synthase
|
–
|
|
|
BRENDA:
BS454222
|
|
|
|
behenoyl-CoA + sphinganine <=> 2-hydroxy-behenoyl_ceramide + CoA
|
2.3.1.298
ultra-long-chain ceramide synthase
|
–
|
|
|
BRENDA:
BS449629
|
|
|
|
sphinganine + behenoyl-CoA <=> N-behenoyl-D-sphinganine + CoA
|
2.3.1.297
very-long-chain ceramide synthase
|
–
|
|
|
BRENDA:
BS448543
|
|
|
|
behenoyl-CoA + sphinganine <=> CoA + N-behenoyl-dihydrosphingosine
|
2.3.1.298
ultra-long-chain ceramide synthase
|
–
|
|
|
BRENDA:
BS449630
|
|
|
|
sphinganine + behenoyl-CoA <=> N-behenoylsphinganine + CoA
|
2.3.1.297
very-long-chain ceramide synthase
|
–
|
|
|
BRENDA:
BS448949
|
|
|
|
behenoyl-CoA + flavin <=> 2-docosenoyl-CoA + reduced_flavodoxin
|
1.3.8.8
long-chain acyl-CoA dehydrogenase
|
–
|
|
|
BRENDA:
BS260358
|
|
|
|
behenoyl-CoA + flavin <=> a_very-long-chain_trans-2,3-dehydroacyl-CoA + reduced_flavodoxin
|
1.3.8.9
very-long-chain acyl-CoA dehydrogenase
|
–
|
|
|
BRENDA:
BR50096
|
|
|
|
behenoyl-CoA + O2 <=> a_very-long-chain_trans-2,3-dehydroacyl-CoA + H2O2
|
1.3.3.6
acyl-CoA oxidase
|
–
|
|
|
BRENDA:
BS388174
|
|
|
|
behenoyl-CoA + sphingosine <=> behenoyl_ceramide + CoA
|
2.3.1.298
ultra-long-chain ceramide synthase
|
–
|
|
|
BRENDA:
BS449628
|
|
|
|
behenoyl-CoA + sphingosine <=> CoA + N-behenoylsphingosine
|
2.3.1.24
sphingosine N-acyltransferase
2.3.1.297
very-long-chain ceramide synthase
2.3.1.298
ultra-long-chain ceramide synthase
|
–
–
–
|
|
|
BRENDA:
BS320744
|
|
|
|
behenoyl-CoA + sphingosine <=> CoA + N-docosanoylsphingosine
|
2.3.1.24
sphingosine N-acyltransferase
|
–
|
|
|
BRENDA:
BS455598
|
|
|
|
behenoyl-CoA + NADPH <=> behenic_aldehyde + NADP+
|
1.2.1.42
hexadecanal dehydrogenase (acylating)
|
–
|
|
|
BRENDA:
BS189216
|
|
|
|
a_very-long-chain_trans-2,3-dehydroacyl-CoA + NADPH + H <=> behenoyl-CoA + NADP+
|
1.3.1.93
very-long-chain enoyl-CoA reductase
|
–
|
B
|
|
BRENDA:
BS442250
|
|
|
|
sphinganine + behenoyl-CoA <=> N-behenoylsphinganine
|
2.3.1.297
very-long-chain ceramide synthase
|
–
|
|
|
BRENDA:
BS448948
|
|
|
|
behenoyl-CoA + phenazine_methosulfate <=> 2-docosenoyl-CoA + reduced_phenazine_methosulfate
|
1.3.8.8
long-chain acyl-CoA dehydrogenase
|
–
|
|
|
BRENDA:
BS260370
|
|
|
|
behenoyl-CoA + lysophosphatidic_acid <=> CoA + 1-acyl-2-behenoyl-sn-glycerol_3-phosphate
|
2.3.1.51
1-acylglycerol-3-phosphate O-acyltransferase
|
–
|
|
|
BRENDA:
BS321046
|
|
|
|
ATP + behenic_acid + CoA <=> AMP + diphosphate + behenoyl-CoA
|
6.2.1.3
long-chain-fatty-acid---CoA ligase
|
–
|
|
|
BRENDA:
BS428229
|
|